以PAC为原料合成锂吸附剂的工艺研究

研究了聚合氯化铝(PAC)为原料合成锂吸附剂的基本工艺路线,并探究了加料方式、反应物配比、反应温度、反应时间和加料速度等对所合成吸附剂吸附量的影响,研究结果表明配比是影响吸附剂吸附量的最主要因素,得到了最佳合成条件,在此条件下所合成吸附剂对锂离子的吸附容量为6.1 mg/g。推断吸附剂的主要成分为晶态或非晶态的LiCl·2Al(OH)_3·nH_2O,同时含有Al(OH)_3、(CaO)_3Al_2O_3·6H_2O及LiCl·H_2O等成分。从吸附结果来看,结晶度较差的片状LiCl·2Al(OH)_3·nH_2O和非晶态的Al(OH)_3为主成分的吸附剂吸附性能最好。     

基于GPS和水准数据的微粒群算法联合反演祁连山北缘断裂三维滑动速率

将微粒群算法与位错理论模型相结合，采用中国地壳运动观测网络提供的青藏高原地区2001~2004年GPS测量数据和2000~2006年水准测量数据，通过常规定权和附有相对权比的方法对祁连山北缘断裂的三维滑动速率进行联合反演，并与蚁群算法反演结果进行对比。结果表明，微粒群算法收敛速度快、稳定性高，结合经典位错理论模型，是一种可以有效求解断层三维滑动速率反演问题的优化算法，在大地测量反演领域极具应用潜力。     

琼东南盆地华光凹陷天然气水合物稳定带厚度的影响因素

为了探讨琼东南盆地华光凹陷海底天然气水合物稳定带的分布规律，定量研究了静水压力、底水温度、地温梯度和气源组分对水合物稳定带的影响程度。在此基础上，分析了华光凹陷现今甲烷水合物稳定带的厚度分布。最后，综合各因素的历史演化过程，初步探讨了华光凹陷1.05 Ma BP以来天然气水合物稳定带的演化。结果表明:(1)气源组分和海底温度的变化对研究区内水合物稳定带的影响较大；水合物稳定带厚度与海底温度呈良好的线性负相关性。(2)水深超过600 m的海域具备形成天然气水合物的温压条件；超过600 m水深的海域水合物稳定带厚度大部分超过 100 m，其中西北部稳定带的最大厚度超过300 m，是有利的水合物勘探区。(3)华光凹陷1.05 Ma BP以来天然气水合物稳定带厚度经历了快速增厚–窄幅变化–快速减薄和恢复的过程。麻坑群与水合物稳定变化敏感区在空间上具有较好的叠合关系。结合前人的研究成果，推测其形成与天然气水合物的分解释放有关。     

Genesis of S-type Granites in the Pengshan Sn-polymetallic Ore Field, Northern Jiangxi Province and its Implications

The Pengshan Sn-polymetallic ore field is located in the southeastern part of the Yangtze block, spanning the southeast edge of the MLYDZ and the northern edge of the mid-segment of the Jiangnan Uplift, and on one side of the MLYDZ. The studies of LA–ICP–MS zircon U–Pb chronology and petrogeochemistry for Early Cretaceous acid granites from the Pengshan ore field were carried out in this paper. We report zircon U–Pb geochronology and whole-rock geochemistry for acid granites in the Pengshan ore field. The zircon U–Pb ages of the muscovite-granite, biotite adamellite and granite-porphyry are 127.6 ± 1.7 Ma, 126.9 ± 1.6 Ma and 126.6 ± 2.0 Ma, respectively. The granites in Pengshan are characterized by a high silicon content and are rich in alkali. They belong to high-potassium, calc-alkaline, peraluminous granite. The rocks have a relatively high Rb/Ba ratio, and the data points for muscovite-granite and biotite adamellite all fall within the clay-rich sources region, near the pelite-derived end-member, showing that the Pengshan muscovite-granite and biotite adamellite mainly originated from the partial melting of metapelites with high maturity. The transformation of the compressional and extensional tectonics in this region approximately 128 Ma obviously lags behind that in the mid-segment of the Jiangnan Uplift (135 Ma), but occurred earlier than the MLYDZ (126 Ma). The Pengshan ore field extends from the mid-segment of the Jiangnan Uplift to the MLYDZ. Although the tectonic stress field is constrained by the combination of the two secondary tectonic units, the time of tectonic system transformation is closer to the MLYDZ because the spatial orientation of the area is enclosed in the MLYDZ. Relevant geophysical and drilling data confirm the rationality of Pengshan–Ao’xia as a multi-center vertical zoning ore field, and show the scientificity of the prospecting idea of abutting joint between the north-west of Pengshan area and the south-east of Ao’xia area.     

A simplified mathematical model for the dam-breach hydrograph for three reservoir geometries following a sudden full dam break

Natural Hazards - The prediction of dam-break water flow at dam site is essential to reduce the potential for loss of damage in the downstream floodplain. In this study, the influence of reservoir...     

连片特困地区易地扶贫移民生计恢复力评估

借鉴社会—生态系统研究领域的恢复力概念，结合可持续生计分析框架和基于资本的评估方法，构建易地扶贫移民生计恢复力评价指标体系。运用陕南安康市3个区县的657份农户实地调研数据，采用因子分析方法和多元线性回归模型，从微观农户视角实证分析和评估易地扶贫移民的生计恢复力及其影响因素。结果表明：易地搬迁农户物质、社会资本分布不均衡，不同搬迁类型和时间对农户生计资本分化产生作用。物质、金融和社会资本积累水平以及环境、健康服务可及性等均是搬迁户提升生计恢复力的前提和基础，而搬迁类型对移民生计恢复力表现出显著的负向作用。建议政府充分发挥政策优势，针对不同搬迁类型和时间移民进行精准帮扶，着力解决搬迁户生计资本的薄弱环节，不断提升其生计恢复潜力。     

Interactive Effects of Ultraviolet Radiation and Dissolved Organic Carbon on Phytoplankton Growth and Photosynthesis in Sanya Bay,Northern South China Sea

Ocean Science Journal - The effects of a simulated climate change scenario, i.e., increased ultraviolet radiation (UVR) and dissolved organic carbon (DOC), on the growth and photosynthesis of...     

金活动态提取剂提取-电感耦合等离子体质谱法测定深穿透地球化学样品中的金

金的地球化学勘查基于金的准确测定,地球化学样品中金含量通常处于ng/g水平,需先进行分离富集,再采用电感耦合等离子体质谱法(ICP-MS)或石墨炉原子吸收光谱法(GFAAS)进行测定。当前,隐伏矿床勘查是地球化学探测技术的发展前沿,金活动态提取技术是寻找隐伏金矿的有效手段之一。相比于全量分析,金的活动态含量更低,需要解决选择性提取、高效预富集与准确测定等一系列难题。本文采用柠檬酸铵与土壤中黏土矿物及次生矿物作用促使吸附和可交换组分的金进入提取液,以硫脲和硫代硫酸钠络合金使活动态金向提取液中扩散,达到选择性提取的目的,建立了提取液中金的预富集及ICP-MS测定方法。实验确定的分析条件为:采用5g/L柠檬酸铵-2g/L硫脲-5g/L硫代硫酸钠为提取剂,提取时间24h,在酸性硫脲介质下用活性炭富集金,金吸附率可达89.6%～109.2%,灰化解吸温度为650～700℃。本方法检出限为0.05ng/g,相对标准偏差(RSD)为9.4%～10.2%,加标回收率为91.2%～93.4%。与已报道的硫酸铁-硫脲-硫代硫酸钠溶液提取再GFAAS测定的方法相比,本方法具有检出限低、测试线性范围宽、测试速度快的优势;应用于森林覆盖区黑龙江东安金矿区地球化学探测试验,金活动态异常与隐伏金矿位置一致。     

基于ROMS和4DVAR的沿轨与网格化SSH数据同化效果评价

Remote sensing products are significant in the data assimilation of an ocean model. Considering the resolution and space coverage of different remote sensing data, two types of sea surface height(SSH) product are employed in the assimilation, including the gridded products from AVISO and the original along-track observations used in the generation. To explore their impact on the assimilation results, an experiment focus on the South China Sea(SCS) is conducted based on the Regional Ocean Modeling System(ROMS) and the four-dimensional variational data assimilation(4 DVAR) technology. The comparison with EN4 data set and Argo profile indicates that, the along-track SSH assimilation result presents to be more accurate than the gridded SSH assimilation, because some noises may have been introduced in the merging process. Moreover, the mesoscale eddy detection capability of the assimilation results is analyzed by a vector geometry–based algorithm. It is verified that, the assimilation of the gridded SSH shows superiority in describing the eddy's characteristics, since the complete structure of the ocean surface has been reconstructed by the original data merging.